Apple seeds contain cyanide, and are easy to get in quantity without raising suspicion. How long does it take? No idea.
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Good luck with your writing! I too have had to search for some very silly things for things I've written! As for slow acting poisons, only ones I could think of that would be really available modernly would be like, antifreeze and such, but I don't think that's so slow acting. And usually it's kids and dogs that get into that.
You could go for Paracetamol/Acetaminophen. The lethal dose is quite low and in theory low enough someone could poison someone else with it. And once symptoms set in people's livers are often beyond rescue and they die a very gruesome death unless we find a transplant organ in time.(And even then survival is not guaranteed)
And it's relatively save to use in writing as it is coated/mixed with enough bittering agent these days that it actually wouldn't work that well to secretly posing someone.
If you need something with a shorter timeframe Methanol is an option.
And of course there's always Dihydrogen monoxide-everyone who has even had one drop of it will die eventually but the time range depends on the dose. With very high doses people die in minutes,with medium doses (this is actually sometimes used by inmates to kill themselves) they die within a day, with lower dose after decades, but some die mere days after they ingested the mere last drop of it. Nasty stuff and very available.
I've now written the scene with death cap mushrooms, but I'll keep this in mind if I decide to change it later. Ty!
Alcohol
I recommend an American diet: ultra-processed foods, excess sodium, saturated fat, refined grains, calories from solid fats and added sugars, and avoid vegetables like the plague! The target will be dead within 50 years...
Go ask chatgpt or something similar for old medical herbs used back in the day that might also posion you. I inspire to write a book one day, and ive found ai to be really informative. The best part is, even if they're wrong its going in a fiction story(i hope) where it wouldn't matter.